ISSN:
1434-6079
Keywords:
32.30
;
32.90
;
35.10
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract From 17 transitions in the singly ionized Sb II spectrum the hyperfine structure (A andB splitting constants) of the complete excited configurations 5p6s and 5p6p were determined by means of optical interference spectroscopy. In addition, a theoretical analysis both of the fine structure and also of the hyperfine structure was carried out (in the case of 5p6p of the general typenpn′p for the first time in literature). For the 3 levels 5p6p 3 P 1, 5p7p 3 D 2 and 5p6p 1 P 1 a different classification was found and consistent values for the fine structure parameters, mixing coefficients and single electron hyperfine structure splitting parametersa nl ik andb nl ik were obtained. The three new determinations in Sb II of the quadrupole moment (in barn) of121Sb (Q(5p6s)=−0.55(5);Q(5p6p)=−0.57(5) from the 5p-electron andQ(5p6p)=−0.7(2) from the 6p-electron) are well agreeing with each other but differ to former values from SbI. The core polarization and isotope shift of the lines, however, are compatible with our former results in SbI.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01436549
