ISSN:
0887-6266
Keywords:
polypropylene
;
nitrile rubber
;
compatibilization
;
dynamic vulcanization
;
dynamic mechanical properties
;
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The effect of blend ratio and compatibilization on dynamic mechanical properties of PP/NBR blends was investigated at different temperatures. The storage modulus of the blend decreased with increase in rubber content and shows two Tg's indicating the incompatibility of the system. Various composite models have been used to predict the experimental viscoelastic data. The Takayanagi model fit well with the experimental values. The addition of phenolic modified polypropylene (Ph-PP) and maleic modified polypropylene (MA-PP) improved the storage modulus of the blend at lower temperatures. The enhancement in storage modulus was correlated with the change in domain size of dispersed NBR particles. The effect of dynamic vulcanization using sulfur, peroxide, and mixed system on viscoelastic behavior was also studied. Among these peroxide system shows the highest modulus. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2309-2327, 1997
Additional Material:
32 Ill.
Type of Medium:
Electronic Resource
