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Some phenomenological consequences of the Doi-Edwards theory of viscoelasticity (1980)

Graessley, William W.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 27-34

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Doi and Edwards have recently proposed a molecular theory for the dynamics of entangled polymer liquids based on a tube model to represent the mutual constraints on configurational rearrangement of the chains. Expressions for diffusion coefficient, plateau modulus, zero-shear viscosity, steady-state recoverable compliance, and terminal relaxation time can be devloped, and relations among these properties that depend only upon observable quantities can be obtained. Several such relations are derived and are compared with experimental observations.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1980.180180103

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