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Effect of polymorphism on the C—H stretching region of the infrared spectrum of polyethylene (1978)

Painter, P. C. ; Runt, J. ; Coleman, M. M. ; [et al.]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 1253-1260

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A complex fine structure in the C—H stretching region of the infrared spectrum of deformed polyethylene single crystals is reported. The deformed crystals are shown to be transformed from the orthorhombic crystal form to a monoclinic structure. The previously deduced C2/m monoclinic structure does not account for the appearance of the new bands. An alternative but similar monoclinic structure is proposed. The symmetry of this structure is consistent with the Fermi resonance interactions required for the observation of these bands.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1978.180160708

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