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Study of exchange reactions in polycarbonate/polyarylcarboxylate mixtures with model compounds (1985)

Devaux, Jacques ; Devaux, Pierre ; Godard, Pierre

New York : Wiley-Blackwell

Die Makromolekulare Chemie 186 (1985), S. 1227-1237

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ISSN: 0025-116X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The exchange reaction between a polycarbonate and a polyarylcarboxylate, both based on bisphenol A, was simulated by studying the reaction between the polycarbonate and diphenyl terephthalate or isophthalate used as model compounds of a polyarylcarboxylate. The kinetic results indicate the presence of a transesterification reaction occurring without any catalyst. Some results from reactions in the melt between both polymers also point to an exchange reaction.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/macp.1985.021860611

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