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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 156 (1972), S. 311-320 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Relationships between the copolymerization rate and the composition of monomer mixture have been evaluated for the following systems : acrylnitrile/methyl acrylate, acrylnitrile/methyl methacrylate, acrylnitrile/α-chloro methyl acrylate, and acrylnitrile/α-bromo methyl acrylate. The copolymerizations were carried out in dimethylformamide at 6O°C in the presence of azobisisobutyronitrile. The constants of cross termination were calculated from the equation of the copolymerization rate.
    Notes: In Abhängigkeit von der Zusammensetzung der Monomermischung wurden für folgende Systeme die Copolymerisationsgeschwindigkeiten in Dimethylformamidlosung bei 60°C gemessen : Acr ylnitril/Methylacrylat, Acrylnitril/Methylmethacr ylat, Acrylnitril/α-Chlor-methylacrylat und Acrylnitril/α-Brom-methylacrylat. Als Initiator diente α.α′-Azobisiso-butyronitril. Die Konstanten für die gekreuzte Abbruchsreaktion wurden aus der Gleichung für die Copolymerisationsgeschwindigkeit berechnet.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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