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Graft copolymers of p-isopropylstyrene and methyl methacrylate (1961)

Matlack, J. D. ; Chinai, S. N. ; Guzzi, R. A. ; [et al.]

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 49 (1961), S. 533-541

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The preparation of a completely isopropylated polystyrene by polymerization of p-isopropylstyrene monomer is described. This polymer was autoxidized in cyclohexane with lauroyl peroxide to give a material of good reproducibility and high purity. Methyl methacrylate was successfully grafted to the polymeric hydroperoxide by using a sugar-containing recipe. Homopolymer was separated from the graft copolymer by extraction. Evidence for grafting was obtained from solubility and fractionation behavior, as well as from light-scattering and viscosity measurements.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1961.1204915232

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