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Photochemistry of phosphonitrilic chlorides. I. A photochemical reaction of low-polymeric phosphonitrilic chlorides (1949)

Dishon, B. R. ; Hirshberg, Y.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 4 (1949), S. 75-82

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Photochemical reactions of trimeric and tetrameric phosphonitrilic chlorides with some hydrocarbons are described. Soluble and insoluble photoreaction products are formed. From the soluble fraction, distillable phenyl- and decahydronaphthyl-phosphonitrilic chlorides were separated; the indistillable and deposit fractions were also found to contain high percentages of carbon and hydrogen. This shows that successive substitution of the chlorine atoms by radicals, R, of the solvents, R—H, had taken place.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1949.120040106

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