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Solution viscosity-molecular weight relationship for polystyrene (1970)

Rogers, Morris G.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 14 (1970), S. 2015-2018

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The 10% solution viscosity has been used extensively as a measure of molecular weight for the commercial production of polystyrene. Recently, poor correlations have been observed between 10% solution viscosity and molecular weight as measured by gel permeation chromatography. Lowering the concentration improves the correlation. At 0.2%, the log-log plot of viscosity versus molecular weight becomes linear.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1970.070140809

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