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Anionic graft polymerization of acrylonitrile and methacrylonitrile on cellulose acetate (1965)

Avny, Yair ; Yom-Tov, Baruch ; Zilkha, Albert

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 9 (1965), S. 3737-3743

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The anionic graft polymerization of AN and MAN on cellulose acetate alkoxide derivative (Li, Na, K) was investigated in THF, DMF, and DMSO. Although the yield of the polymerization was high the extent of grafting of acrylonitrile was low (1.4-5.3% in DMF and DMSO and 20% in THF) due to homopolymerization caused by chain transfer to monomer. With methacrylonitrile which has no acidic α-hydrogen the amount of grafted monomer was higher (37-72%).

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1965.070091120

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