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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 210 (1993), S. 129-141 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Blends aus Poly-ε-caprolacton (PCL) und Poly(β-hydroxybyurat-co-β-hydroxyvalerat) (PHBV) mit 4 mol-% Hydroxyvalerat-Anteil wurden durch Mischen der Polymeren sowohl ohne Initaiator als auch in Gegenwart von Dicumylperoxid (DCPO) bei 160°C oder Dibenzoylperoxid (DBPO) bei 100°C hergestellt. Es wurden PCL/PHBV-Blends mit dez Zusammensetzungen 30/70 und 70/30 Gew.-% hergestellt. Zum vergleich wurden diereinen Polymeren ebenfallsmit DCPO bei 160°C umgesetzt. Die Produkte wurden thermisch (DSC) und Mechanisch (Zugversuche) sowie mittels Rasterrelektronenmikroskipie (SEM) untersucht. SIgnifikateUnterschiedein den chemisch-physialischen Eigenschaften der Beldns Konnten auf den Einfluß sowohl des Initiators als auch der Temperatur zurückegeführt werden.
    Notes: Blends of poly-ε-caprolactone (PCL) and poly(β-hydroxybutyrate-co-β-hydroxy-valerate) (PHBV) containing 4 mol-% of hydroxyvalerate were prepared by mixing the two polymers in the presence of either dicumylperoxide (DCPO) at 160°C or dibenzoylperoxide (DBPO) at 100°C. Similarly, blends were obtained by mixing the two polymers without any peroxide added. The blends were prepared in to complementary compositions, namely 70 wt.-% PCL/30 wt.-% PH BV and 30 wt.-% PCL/70 wt.-% PHBV, respectively. Also pure polymers were reacted with DCPO at 160°C in the same way as the blends.Thermal (DSC), mechanical (tensile tests) and SEM analyses were performed on the blends and on the pure polymers.Significant differences were found in the chemical-physical characteristics of blends with and with out peroxides as well as in blends prepared at low and high temperatures.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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