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A novel copolymerization reaction (1968)

Meyers, R. A. ; Wilson, E. R.

New York : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Letters 6 (1968), S. 531-534

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ISSN: 0449-2986

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A new addition polymerization reaction is described which involves the copolymerization of sulfur dichloride or sulfur monochloride with a diolefin. Sulfur dichloride copolymerizes with bis(1,2,3,6-tetrahydrophthalimide) (A) to form poly[N,N′-m-phenylenebis(3,4-dicarboxy-6-chlorocyclohexyl) sulfide imide] (I). Sulfur monochloride copolymerizes with A to form poly[N,N′-m-phenylenebis(3,4-dicarboxy-6-chlorocyclohexyl) disulfide imide] (II). The polyimides, I and II were characterized by elemental analysis, infrared spectroscopy, and inherent viscosity. The mechanism of polymerization is discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1968.110060714

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