ISSN:
0449-2978
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Samples of cis-polybutadiene were cross-linked in the presence of decalin at values of φr (the volume fraction of rubber) ranging from 0.25 to 0.50. After the diluent had been removed, a study was made of the force-extension and thermoelastic behavior of the networks. Within experimental error, the ratio of the Mooney-Rivlin constants 2C2/2C1 was found to be zero for networks prepared at low φr (0.25 and 0.30) but started to increase towards the conventional value at higher φr. The quantity fe/f was found to be independent of the ratio 2C2/2C1 and of the extension ratio α; the average value of fe/f was found to be 0.11.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1972.160100602