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Measurement of hydrogen isotope transport in poly(vinyl fluoride) films by the permeation-rate method (1969)

Ziegel, K. D. ; Frensdorft, H. K. ; Blair, D. E.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 809-819

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ISSN: 0449-2978

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A novel gas-flow method of measuring the diffusion, solubility, and permeability of gases and vapors in polymer films is described. The specific advantages of this system over the time-lag technique are discussed. Transport data, including activation energies and enthalpies of solutions, for hydrogen and deuterium in poly(vinyl fluoride) are presented, and the effects of the glass transition and of orientation on the observed transport rates are discussed.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1969.160070506

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