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  • 1
    Electronic Resource
    Electronic Resource
    Block copolymers from isobutyl vinyl ether and 2-chloroethyl vinyl etherDedicated to Peter H. Plesch on the occasion of this 80th birthday (1998)
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 607-612 
    Details
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Scope and limitation of the vinyl ether block copolymerization of isobutyl vinyl ether (IBVE) and 2-chloroethyl vinyl ether (CEVE) initiated by CH3CHIOR/ZnI2 were studied. These polymerizations exhibit the characteristics of a living polymerization. Di- and triblock copolymers were synthesized by sequential monomer addition (IBVE, CEVE). The poly(2-chloroethyl vinyl ether) (PCEVE) segment in those block copolymers is of particular interest because of the possibility to modify this segment by nucleophilic substitution of the chlorine. This strategy allows the synthesis of tailor made amphiphilic block copolymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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