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Cationic polymerization of glycidyl phenyl ether initiated by various arylsulfonium salts as new thermal latent cationic initiators (1998)

Shimomura, Osamu ; Tomita, Ikuyoshi ; Endo, Takeshi

Weinheim : Wiley-Blackwell

Macromolecular Rapid Communications 19 (1998), S. 493-497

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ISSN: 1022-1336

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The cationic initiation activity of derivatives of S-methylsulfonium salts has been evaluated in the cationic polymerization of glycidyl phenyl ether (1). These initiators are soluble in 1 and capable of initiating the cationic polymerization of 1 on heating, except for methyltetrahydrothiophenium tetrafluoroborate (6) (r.t. -160°C). Among them, methyldiphenylsulfonium tetrafluoroborate (4) shows moderate thermal latency, that is the polymerization of 1 occurs efficiently at 160°C but not below 80°C.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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