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  • 1
    Electronic Resource
    Electronic Resource
    “Living radical” polymerization of styrene in the presence of a nitroxide compound (1996)
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 17 (1996), S. 683-691 
    Details
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of parameters such as styrene dilution and active site concentration on the polymerization of styrene in the presence of a di-tert-butyl nitroxide adduct (A-T) was examined. It is confirmed that the rate of styrene polymerization is independent of A-T concentration, with no monomer dilution effect. An increase in radical concentration generated in the medium leads to faster propagation, but the molecular weight of the polymers formed is alway controlled by the A-T concentration.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/marc.1996.030171003
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