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Comparative recalculation of the monomer reactivity ratios in copolymerization for styrene and methyl methacrylate (1983)

Leicht, R. ; Fuhrmann, J.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 2215-2224

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The monomer reactivity ratios (MMRs) in radical copolymerization for styrene and methyl methacrylate were recalculated by five different methods using literature copolymerization data. The use of approximate 95% confidence limits and their visual inspection helps to separate possibly biased copolymer composition data. The recalculated mean MRR values were r1 (styrene) = 0.501 ± 0.031 and r2 = 0.472 ± 0.031. The results of the linear least-squares calculation procedures seldom approach the quality of the nonlinear least-squares analysis according to the method of Tidwell and Mortimer.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1983.170210806

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