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Aqueous polymerization of methacrylamide (1981)

Shukla, J. S. ; Tiwari, R. K.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 1517-1524

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The aqueous polymerization of methacrylamide (I) initiated by KBrO3-thioglycolic acid (TGA) has been studied at 30 ± 0.2°C in nitrogen. The rate is given by K[M]1.19 [thioglycolic acid]1 [KBrO3]0.53 for 10-15% conversion. Activation energy was found to be 53.96 kJ/mole (12.92 kcal/mole) in the investigated range of temperature 30-45°C. The role of addition of a series of aliphatic alcohols and some salts was also determined. The kinetics of polymerization was followed iodometrically.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1981.170190622

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