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  • 1
    Electronic Resource
    Electronic Resource
    Reactivity of 4-halogeno 1-vinyl naphthalenes in cationic polymerization (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 1995-2000 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Improved methods for the synthesis of 4-halogeno 1-vinylnaphthalenes are proposed. Reactivity ratios are determined for the following systems: 4-fluoro-1-vinyl naphthalene-styrene, 4-chloro-1-vinyl naphthalene-styrene, and 4-bromo-1-vinyl naphthalene-styrene. The determinations are performed at various specific temperatures and the relative activation parameters are obtained. It appears that the reactivity of 1-vinyl naphthalene is drastically decreased when substituted by a halogen. In the case of 1-vinyl naphthalene the selection is enthalpically controlled.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180634
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