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  • 1
    Electronic Resource
    Electronic Resource
    Radiation-induced polymerization at high dose rate. I. Isobutyl vinyl ether in bulk (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 179-189 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bulk polymerization of isobutyl vinyl ether was studied at 25°C in a wide dose rate range, 8.2-277 rad/sec by γ rays and 8.8 × 103-2.2 × 105 rad/sec by electron beams. At low dose rate, 8.2-277 rad/sec, only the radical polymerization took place. At high dose rate exceeding 8.8 × 103 rad/sec, cationic polymerization was found to occur in addition to the radical polymerization. DPn of the product at high dose rate was 9-10. Further drying of the monomer increased Rp, and molecular weight of the product formed by cationic mechanism also increased.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180117
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