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Effect of inititiator on the molecular weight distribution in dispersion polymerization of styrene (1980)

Almog, Yaacov ; Levy, Moshe

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 1-11

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Dispersion polymerization of styrene in the particle size range of 10 μ with lauroyl peroxide as initiator results in a double-peak molecular weight (MW) distribution. The high-MW fraction was due to emulsion polymerization. The same phenomenon also exists in AIBN and benzoyl peroxide initiation, although it is less obvious. The kinetics of the reaction for dispersion polymerization was dependent on the concentration of the dispersing agent and the nature of the initiator.

Additional Material: 12 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1980.170180101

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