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  • 1
    Electronic Resource
    Electronic Resource
    Photolysis of poly(ethyl acrylate) and poly(n-butyl acrylate) in vacuo (1974)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 1541-1547 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thin films of poly(ethyl acrylate) and poly(n-butyl acrylate) were decomposed in vacuo by means of a high pressure Hg lamp, and the rate of development of volatile products was measured. The main gaseous products were CO, CO2, and the alcohol, aldehyde, alkane, and formate derived from the respective ester groups. In addition poly(ethyl acrylate) evolved acetal as well as ethyl propionate, while n-butyl valerate was evolved from poly(n-butyl acrylate) only after prolonged exposure. All products and the principal features of the decomposition are discussed.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1974.170120716
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