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Kinetics of polymer decomposition (1973)

Danforth, Joseph D. ; Takeuchi, Tsugio

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 2083-2090

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Kinetic equations have been developed for polymers that decompose by the zipper mechanism. The usual assumption of steady state kinetics has not been made. Plots of the fraction decomposed α, as a function of time demonstrate a variety of patterns depending upon the relative values of the fraction k1, of chains becoming activated per second and the fraction k2 of an activated chain that decomposes per second.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1973.170110901

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