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A vivid model illustrating chiral recognition induced by achiral structures (1990)

Davankov, Vadim A. ; Meyer, Veronika R. ; Rais, Maya

New York, NY [u.a.] : Wiley-Blackwell

Chirality 2 (1990), S. 208-210

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ISSN: 0899-0042

Keywords: enantioselectivity ; three-point model ; didactic model ; chiral separations ; ligand-exchange chromatography ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: If diastereomeric complexes are adsorbed on a surface or if they include a molecule of solvent, two points of attractive interaction between the chiral species of the complex can be sufficient for mutual chiral recognition of these species. In special cases even one single point of interaction is sufficient. This extension of the three-point contact rule of Dalgliesh, first observed in chiral ligand-exchange chromatogrphy, can be demonstrated by using hands.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/chir.530020403

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