ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Proceed order?

Export
  • 1
    ISSN: 0044-2313
    Keywords: Potassium dithiocarbiminate ; dithiolates ; X-ray structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of [ImNCS2K] (ImN = 1,3-Dimethylimidazoline-2-imino): a Novel Potassium DithiocarbiminateThe reaction of the 2-iminoimidazoline 4 with KMe gives the potassium imidate 7 from which the potassium 1,1-dithiolate 8 is obtained in almost quantitative yield. Crystals of C6H8N3S2K · 1/6 CH3CN (8 · 1/6 CH3CN) are triclinic, space group P1, Z = 6, a = 10.988(4), b = 13.597(8), c = 13.622(9) Å, α = 113.003, β = 105.53(3), γ = 105.62(3)°, V = 1636.90 Å3. The structure consists of a complicated 3-dimensional framework in which the K2 units bridged by the four sulfur atoms of two thiolate ligands are connected by nitrogen and sulfur bridges.
    Notes: Die Umsetzung des 2-Iminoimidazolins 4 mit KMe ergibt das Kaliumimidat 7, aus dem das Kalium-1,1-dithiolat 8 in fast quantitativer Ausbeute erhältlich ist. C6H8N3S2K · 1/6 CH3CN (8 · 1/6 CH3CN) kristallisiert triklin, Raumgruppe P1, Z = 6, a = 10.988(4), b = 13.597(8), c = 13.622(9) Å, α = 113.00(3), β = 105.53(3), γ = 105.62(3)°, V = 1636.90 Å3. Die komplexe Raumnetzstruktur besteht aus den durch die 4 Schwefelatome zweier Dithiolat-Liganden verbrückten K2-Einheiten, die ihrerseits über Stickstoff- und Schwefelatome verbunden sind.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...