ISSN:
0044-2313
Keywords:
Ternary metal selenides
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
K3BiSe3, Rb3BiSe3, and Cs3BiSe3 - Derivatives of the Th3P4 Structure TypeThe compounds K3BiSe3, Rb3BiSe3, and Cs3BiSe3 were synthesized by heating mixtures of Bi2O3 and the respective alkalicarbonate in a stream of hydrogen saturated by selenium at 850°C. Thin crystals of the compounds appear red in transmitted light. They crystallize isostructural with Na3AsS3, space group P213, lattice constants a = 9.771(5) Å, a = 10.161(3) Å, and a = 10.587(5) Å for K3BiSe3, Rb3BiSe3, and Cs3BiSe3, respectively. The Na3AsS3 structure type is a derivative of the Th3P4 structure type.
Notes:
Die Darstellung der Verbindungen K3BiSe3, Rb3BiSe3 und Cs3BiSe3 gelang durch Umsetzungen von Bi2O3 mit dem entsprechenden Alkalicarbonat in einem mit Selen beladenen Wasserstoffstrom bei 850°C. Die Verbindungen erscheinen im Durchlicht rot und kristallisieren im Na3AsS3-Typ (Raumgruppe P213) mit den Gitterkonstanten a = 9,771(5) Å für K3BiSe3, a = 10,161(3) Å für Rb3BiSe3 und a = 10,587(5) Å für Cs3BiSe3. Es handelt sich um Substitutionsderivate des Th3P4-Typs.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19966220613
