ISSN:
0044-2313
Keywords:
Boranes
;
Borazanes
;
Organoboron chelate compounds
;
n.m.r.-spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Properties of N,N-Dialkyl-allylaminoboranes and N,N-DimethylaminopropylboraneComplexes of the type H3B ← NR2(CH2CH=CH2) (R=CH3 I, C2H5 II) are formed by reaction of Li[BH4] with dialkylallylammonium salts. By addition of AlCl3 I can be transformed into the chelate-stabilized N,N-dimethyl-aminopropylborane III. The i.r.-, 1H, 13C-n.m.r. and mass-spectra of I-III are reported and discussed.
Notes:
Bei der Einwirkung von Li[BH4] auf Dialkylallyl-ammonium-Salze entstehen Addukte des Typs H3B ← NR2(CH2CH=CH2) (R=CH3 I, C2H5 II). I reagiert bei Zugabe von AlCl3 zum chelatstabilisierten N,N-Dimethyl-aminopropylboran III. - Die IR-, 1H- und 13C-NMR- sowie M-Spektren von I-III werden mitgeteilt und diskutiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210117
