ISSN:
0044-2313
Keywords:
Dichalcogenolenchelates
;
conducting materials
;
x-ray
;
EPR
;
dmit isologues
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Syntheses and Properties of Molecular Conductors based on dmit isologous Chelates. Crystal and Molecular Structure of Tetramethylammonium-bis-[bis(1,3-dithiole-2-selone-4,5-diselenolato)nickelate]; [(CH3)4N] [Ni(dsise)2]2Syntheses and properties of dichalcogenolate chelates of the general type [(CH3)4N]n[ML2] (n ≤ 2; M = Ni, Pd, Pt); L = dmit (1,3-dithiole-2-thione-4,5-dithiolate), dmise (1, 3-dithiole-2-selone-4,5-dithiolate), dsit (1, 3-dithiole-2-thione-4,5-diselenolate), dsise (1, 3-dithiole-2-selone-4,5-diselenolate), dsis (1, 3-diselenole-2-selone-4,5-diselenolate) are reported. The effects of the chalcogen atom variation in these chelates are discussed by using UV/VIS, IR, EPR, cyclovoltammetric and conductivity data. The x-ray structure of [(CH3)4N][Ni(dsise)2]2 (space group Pccn, a = 7.427(1), b = 39.144(5), c = 11.836(1) Å) and the conductivity of the crystal (12 S cm-1 at room temperature) are given.
Notes:
Synthese und Eigenschaften von Dichalkogenolat-Chelaten vom Typ [(CH3)4N]n[ML2] mit n ≤ 2; M = Ni, Pd, Pt und L = dmit (1, 3-Dithiol-2-thion-4,5-dithiolat), dmise (1,3-Dithiol-2-selon-4,5-dithiolat), dsit (1,3-Dithiol-2-thion-4,5-diselenolat), dsise (1,3-Dithiol-2-selon-4,5-diselenolat) und dsis (1, 3-Diselenol-2-selon-4, 5-diselenolat) werden beschrieben. Anhand von UV/VIS-, IR-, EPR-, cyclovoltammetrischen und Leitfähigkeitsuntersuchungen werden die Auswirkungen der Chalkogenvariation in den Chelaten diskutiert. Die röntgenkristallographischen Daten von [(CH3)4N] [Ni(dsise)2]2 (Raumgruppe Pccn, a = 7,427(1), b = 39,144(5), c = 11,836(1) Å) und die Kristalleitfähigkeit (12 S cm-1, Raum-temperatur) werden vorgestellt.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19946200115
