ISSN:
0044-2313
Keywords:
Sulfenium Salts
;
Preparation
;
Vibrational Spectra
;
NMR-Spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The Synthesis of the Dichloromethylene-halogenosulfenium Salts Cl2CSCl+ AsF6- and Cl2CSBr+ AsF6-The sulfenium salts Cl2CSCl+ AsF6- and Cl2CSBr+ AsF6- are synthesized by oxidative halogenation of thiophosgene, Cl2CS with X2/AsF5 (X = Cl, Br) at 195 K and are characterized by vibrational as well as NMR spectroscopy.
Notes:
Die Sulfeniumsalze Cl2CSCl+ AsF6- und Cl2CSBr+ AsF6- werden aus Thiophosgen Cl2CS durch oxidative Halogenierung mit X2/AsF5 (X = Cl, Br) bei 195 K dargestellt und schwingungs- sowie NMR-spektroskopisch charakterisiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936190325
