ISSN:
0044-2313
Keywords:
Tris(fluoraryl)boranes
;
preparation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Properties of New Tris(fluoroaryl)boranesB(2-FC6H4)3, B(4-FC6H4)3, B(2,6-F2C6H3)3 and B(C5F4N)3 are prepared from the reactions of RMgX with boron trifluoride, B(OC6F5)3 and B(SC6F5)3 from C6F5XH (X = O, S) and boron trichloride. The synthetic routes and the properties of these mainly new compounds are described.
Notes:
B(2-FC6H4)3, B(4-FC6H4)3, B(2,6-F2C6H3)3 und B(C5F4N)3 werden durch Reaktionen von RMgX mit Bortrifluorid, B(OC6F5)3 und B(SC6F5)3 aus C6F5XH (X = O, S) mit Bortrichlorid dargestellt. Die Syntheseverfahren und die Eigenschaften der meist neuen Verbindungen werden beschrieben.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926180113