ISSN:
0044-2313
Keywords:
Ternary nickelphosphides
;
magnesium
;
manganese
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Mg3Ni20P6 and Mn3Ni20P6 - Two new Phosphides with Cr23C6-type StructureThe crystal structures of Mg3Ni20P6 (a = 11.113(3)A) and Mg3Ni20P6 (a = 11.085(1)Å) were determined by single crystal X-ray investigations. Both compounds, prepared by heating appropriate mixtures of the elements, crystallize in a ternary variant of the Cr23C6-type structure (Fm3m), which is well-known due to a large number of ternary borides.
Notes:
Die Kristallstrukturen von Mg3Ni20P6 (a = 11,113(3) Å) und Mn3Ni20P6 (a = 11,085(1) Å) wurden röntgenographisch mit Einkristallmethoden bestimmt. Beide Verbindungen, dargestellt durch Erhitzen entsprechender Elementgemenge, bilden eine Besetzungsvariante der Cr23C6-Struktur (Fm3m), in der viele ternäre Boride kristallisieren.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926180107
