ISSN:
0044-2313
Keywords:
Rhodium(III) complex
;
tris(N,N-diethyl-N′-benzoylthioureato)rhodium(III)
;
preparation
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Crystal Structure of Tris(N,N-Diethyl-N′-benzoylthioureato) Rhodium(III)Rh(C12H15N2OS)3 crystallizes in the trigonal space group P-3. The cell parameters are a = 16.660(2), c = 8.479(1) Å and Z = 2. The structure was solved with Patterson and direct methods and refined to a final R-value of 7.05%. RhIII is octahedrally coordinated to three N,N-Diethyl-N′ -benzoylthiourea molecules, which are bidentately coordinated through their oxygen and sulfur atoms. The Rh—S and Rh—O bond lengths are 2.284 Å and 2.033 Å, respectively.
Notes:
Rh(C12H15N2OS)3 kristallisiert in der trigonalen Raumgruppe P-3 mit den Gitterkonstanten a = 16,660(2), c = 8,479(1) Å, Z = 2. Die Struktur wurde mit Patterson und Direkten Methoden gelöst und bis zu einem R-Wert von 7,05% verfeinert. RhIII bildet mit dem Liganden N,N-Diethyl-N′ -benzoylthioharnstoff einen oktaedrisch koordinierten Neutralkomplex, in dem drei Ligandmoleküle bidental über Schwefel und Sauerstoff an das Zentralatom gebunden sind. Der Rh—S-Abstand beträgt 2,284 Å, der Rh—O-Abstand 2,033 Å.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926150918
