ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Transition Metal Peroxofluoro Complexes. IX. Crystal Structure of Ba3[Ti(O2)F5]2 · 2 H2OThe pale yellow hydrat Ba3[Ti(O2)F5]2 · 2 H2O crystallizes tetragonal (space group P42/mbc, a = 1 248.5(3), c = 812.2(2) pm; Z = 4; R = 0.026 for 404 independent reflections). It contains isolated [Ti(O2)F5]3- anions. Thermal decomposition leads directly to α-Ba3Ti2O2F10, which is isotypic to α-Ba3Al2F12.
Notes:
Das hellgelbe Hydrat Ba3[Ti(O2)F5]2 · 2 H2O kristallisiert tetragonal (Raumgruppe P42/mbc, a = 1 248,5(3), c = 812,2(2) pm; Z = 4; R = 0,026 für 404 unabhängige Reflexe) und enthält isolierte [Ti(O2)F5]3--Anionen. Die thermische Zersetzung führt direkt zum α-Ba3Ti2O2F10, das isotyp zum α-Ba3Al2F12 kristallisiert.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19895750123
