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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 539 (1986), S. 211-218 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: I.R.-Spectroscopic Investigation of the Interaction between Ni-containing Y-Zeolites and Carbon MonoxideBy the interaction of CO with reduced NiNaY or NiHY samples adsorbed CO on Ni2+ (2 215 cm-1) and on Ni+ (2 085 and 2 095 cm-1, respectively) and two species of adsorbed Ni(CO)4 are formed. Ni(CO)4 is produced in a slow, reversible reaction. Both species are in an equilibrium which is influenced by the acidity of the samples.
    Notes: Bei der Einwirkung von CO auf reduzierte NiNaY- und NiHY- Zeolithe beobachtet man adsorbiertes CO an Ni2+ (2 215 cm-1) und an Ni+ (2 085 bzw. 2 095 cm-1) sowie zwei Formen von adsorbiertem Ni(CO)4. Ni(CO)4 wird in einer langsamen, reversiblen Reaktion gebildet. Die beiden Formen stehen in einem durch die Acidität der Proben beeinflußten Gleichgewicht.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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