ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Oxychlorides under Reducing Conditions: Single Crystals of NdOCl and GdOClSingle crystals of NdOCl and GdOCl are obtained in metallothermic reduction reactions of NdCl3 and GdCl3, respectively, with sodium due to ubiquitous oxidic impurities by crystallization from the melt. The crystal structures of NdOCl [a = 402.49(2), c = 678.37(5) pm] and GdOCl [a = 394.95(3), c = 667.08(7) pm], both PbFCl structure type (P4/nmm, Z = 2) were refined.
Notes:
Bei der metallothermischen Reduktion von NdCl3 bzw. GdCl3 mit Natrium werden, durch kaum vermeidbare oxydische Verunreinigungen bedingt, Einkristalle von NdOCl bzw. GdOCl durch Kristallisation aus der Schmelze erhalten. Die Kristallstrukturen (PbFCl-Typ, P4/nmm, Z = 2) wurden verfeinert. Es ist: a = 402,49(2); c = 678,37(5) pm (NdOCl) und a = 394,95(3); c = 667,08(7) pm (GdOCl).
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19865330222
