ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Crystal and Molecular Structure of Tetra-n-butylammonium N-Methyl-N-Thioformyl Dithiocarbamate[N(n-C4H9)4][S2C—N(CH3)—CS—H] crystallizes in the triclinic space group P1 (Z = 2) with cell dimensions (-45°C) a = 9.185(2) Å, b = 10.263(3) Å, c = 13.301(3) Å, α = 101.73(2)°, ß = 99.59(2)°, γ 100.57(2)°. The crystal structure was solved by means of direct methods and refined to a conventional reliability index R = 0.066 (Rω = 0.070). 5945 independent intensities being measured.
Notes:
[N(n-C4H9)4][S2C—N(CH3)—CS—H] kristallisiert triklin in der Raumgruppe P1, Z = 2; Gitterdimensionen (-45°C): a = 9,185(2) Å, b = 10,263(3) Å, c = 13,301(3) Å, α = 101,73(2)°, ß = 99,59(2)°, γ = 100,57(2)°. Die Kristallstruktur wurde mit Hilfe direkter Methoden gelöst und bis zu einem konventionellen Gütefaktor von R = 0,066 (Rω = 0,070) verfeinert, bei 5945 unabhängigen Meßreflexen. In der Struktur liegen isolierte [N(n-C4H9)4]+-Kationen und [S2C—N(CH3)—CS—H]--Anionen vor.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19865320115
