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Na6Si2Se8: Ein Perselenidosilicat (1985)

Eisenmann, Brigitte ; Hansa, Jendy ; Schäfer, Herbert

Weinheim : Wiley-Blackwell

Zeitschrift für anorganische Chemie 526 (1985), S. 55-59

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ISSN: 0044-2313

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: On Na6Si2Se8, the First Perselenido SilicateThe new compound Na6Si2Se8 crystallizes in the monoclinic system, space group P21/c (No. 14) with lattice constants see „Inhaltsübersicht“. Two SiSe4 tetrahedra are connected by a Se-Se covalent bond, forming a discrete [Si2Se8]6- anion.

Notes: Die neue Verbindung Na6Si2Se8 kristallisiert monoklin in der Raumgruppe P21/c (Nr. 14) mit den Gitterkonstanten a = 727,1(3) pm, b = 1700,7(5) pm, c = 1378,3(4) pm, β = 99,44(8)°. In der Struktur sind zwei SiSe4-Tetraeder über eine Se-Se-Bindung zu diskreten [Si2Se8]6--Anionen verknüpft.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/zaac.19855260708

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