ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
X-Ray Structure Analysis of the Triply Thiolato Bridged Complexes Tricarbonylmolybdenum-tris(μ2-t-butylthio)-η7-cycloheptatrienylmolybdenum, (CO)3Mo(μ2-SC(CH3)3)3Mo-η7-C7H7 and Tricarbonylmolybdenum-tris(μ2-n-butylthio)-η7-cycloheptatrienylmolybdenum, (CO)3MO(μ2-SC4H9)3Mo-η7-C7H7The crystal and molecular structures of the isomeric complexes (CO)3Mo(μ2SC-(CH3)3)3Mo- η7-C7H7 and (CO)3MO(μ2-SC4H9)3Mo- η7-C7H7 have been determined by means of X-ray structure analysis. In both compounds the arrangement of the central Mo2S3 unit deviates considerably from the expected D3h-symmetry.
Notes:
Die Kristall- und Molekülstruktur der isomeren Komplexe (CO)3Mo(μ2-SC(CH3)3)3Mo- η7-C7H7 und (CO)3Mo(μ2-SC4 H9)3Mo-η7-C7H7 wurden mittles Röntgenstrukturanalyse ermittelt. In beiden Verbindungen weicht die Anordnung der Mo2S3-Einheit stark von der erwarteten D3h-Symmetrie ab.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794550104