ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Spectroscopic Investigations of Mono- and Binuclear Metalcarbonyl Complexes of Tetraalkyldistibane and Tetraphenyldistibane LigandsThe reactions of photochemically generated solutions of pentacarbonyl (tetrahydrofurane)chromium and -tungsten with tetramethyldistibane 1, tetraethyldistibane 2, tetra-tert-butyldistibane 3, and tetraphenyldistibane 4 yield mononuclear complexes (OC)5M—SbR2SbR2 (5; M = Cr, W; R = CH3, C2H5, C6H5) and binuclear complexes (OC)5M—SbR2SbR2—M(CO)5 (6; M = Cr, W; R = t-C4H9, C6H5). The chemical and spectroscopic properties of these compounds are discussed.
Notes:
Aus photochemisch erzeugten Lösungen von Pentacarbonyl(tetrahydrofuran)-chrom und -wolfram bilden sich mit Tetramethyldistiban 1, Tetraethyldistiban 2, Tetra-tertbutyldistiban 3 und Tetraphenyldistiban 4 einkernige Komplexe des Typs (OC)5M—SbR2SbR2 (5; M = Cr, W; R = CH3, C2H5, C6H5) sowie zweikernige Komplexe (OC)5M—SbR2SbR2—M(CO)5 (6; M = Cr, W; R = t-C4H9, C6H5). Die chemischen und spektroskopischen Eigenschaften dieser Verbindungen werden diskutiert.
Additional Material:
7 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794540124
