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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 452 (1979), S. 103-111 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Formation of Three-coordinated Sulfur (VI)-Nitrogen Compounds from NSF3From NSF3 and LiN(SiR3)CR3 the three-coordinated sulfur(VI)-nitrogen compounds S(=NSiR3) (=NCR3)2 (8) and S(=NCR3)3 (9) are formed. With less bulky amines only polymerisation products are observed. The mechanism for the formation of 8 and 9 is discussed and some reactions of 8 and 9 are reported.
    Notes: Aus NSF3 und LiN(SiR3)CR3 bilden sich die dreifach-koordinierten Schwefel(VI)-Stickstoff-Verbindungen S(= NSiR3) (=NCR3)2 (8) und S(=NCR3)3 (9). Mit weniger sperrigen Aminen werden nur Polymere beobachtet. Der Bildungsmechanismus für 8 und 9 wird diskutiert und über einige Reaktionen von 8 und 9 berichtet.
    Type of Medium: Electronic Resource
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