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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 429 (1977), S. 131-136 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Enthalpies of Mixing of Liquid Copper(I)-Halide-Chalkogen SystemsThe integral enthalpies of mixing of liquid CuCl(Br)-Se(Te) mixtures were determined in an isoperibolic calorimeter at temperatures of 766 and 818 K for tellurium and 818 K for selenium mixtures. The selenium systems are endothermic, the tellurium systems exothermic. The absolute value of the enthalpy of mixing of the tellurium systems decreases with increasing temperatures. The endothermic resp. exothermic behaviour of these systems is interpreted in terms of the structure of these melts.
    Notes: Die Mischungsenthalpien von flüssigen CuCl(Br)-Se(Te)-Mischungen wurden in einem isoperibolen Reaktionscalorimeter bei 766 K und 818 K (Te) bzw. 818 K (Se) bestimmt. Die selenhaltigen Systeme zeigen endotherme, die tellurhaltigen exotherme Effekte. Mit steigender Temperatur streben die Mischungsenthalpien der Tellursysteme gegen null. Das exotherme bzw. endotherme Verhalten wird mit Hilfe der Struktur der Schmelzen gedeutet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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