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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 423 (1976), S. 35-39 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of Trimethyltin Methanesulfinate, (CH3)3SnO2SCH3Trimethyltin methanesulfinate, (CH3)3SnO2SCH3 crystallizes orthorhombie in the space group A2122. The lattice constants are: a = 7.98 ± 0.01, b = 12.59 ± 0.02 and c = 17.83 ± 0.02 Å Within the crystal structure the Sn atoms are linked together via bridging RSO2 groups to form a helical chain along [l00]. Each Sn atom is surrounded by three C and two 0 atoms in a trigonal bipyramidal arrangement. The Sn—C distances are in the range from 2.09 to 2.18 Å the Sn—0 distance amounts to 2.23 Å.
    Notes: Trimethýlzinn-methansulfinat, (CH3)3SnO2SCH3 kristallisiert orthorhombisch in der Raumgruppe A2122 mit den Gitterkonstanten a = 7,98 ± 0,01, b = 12,59 ± 0,02 und c = 17,83 ± 0,02 Å. In der Kristallstruktur sind die Sn-Atome über RS02-Brücken zu schraubenförmigen Ketten längs [100] verknüpft. Jedes Sn-Atom ist von drei C- und zwei 0-Atomen trigonalbipyramidal umgeben. Die Sn—C-Abstände liegen zwischen 2,09 und 2,18 Å, der Sn—0-Abstand beträgt 2,23 Å.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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