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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 400 (1973), S. 148-160 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Condensation Reactions of the Monomeric Silicic AcidThe condensation of monomeric silicic acid in 0.084, 0.4 and 0.97 M aqueous HCl containing solution is investigated by means of chemical, kinetical, and chromatographic methods. The Condensation, in dependence on the time, proceeds via the di-, cyclotri-, cyclotetra- and cyclohexa- or double threering-silicic acid as intermediates, leading to two- and threedimensional highmolecular silicic acids which are not of the known types as doubles chain or phyllosilicate structures.
    Notes: Mit Hilfe Chemischer, kinetischer und Chromatographischer Methoden wird gezeigt, daß die Monokieselsäure in 0,084;0,4 und 0,97 m salzsaurer wäßriger Lösung in Abhängigkeit von der Zeit über die Di-, Cyclotri-, Cyclotetra- und Cyclohexa-bzw. Doppeldreiringkieselsäure zu zwei- bis dreidimensionalen hochmolekularen Kieselsäuren kondensiert, die nicht die Konstitution von Doppelketten- oder Phyllokieselsäuren haben.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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