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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The N2O decomposition on Li2O-; and Ga2O3-doped ZnO was investigated. The electrical conductivity of the samples has been measured before and during catalysis. The effects are discussed on the basis of the energy resonance hypothesis of heterogeneous catalysis. A correlation between catalytic activity, activation energy of the homogeneous reaction, electron impact experiments described in the literature, and the activation energy of the electrical conductivity of the substances was found.
    Notes: An mit Li2O bzw. Ga2O3 dotierten Zinkoxid wurde der N2O-Zerfall untersucht. Im Zusammenhang mit an den Substanzen vor und während der Katalyse durchgeführten elektrischen Leitfähigkeitsmessungen werden die Ergebnisse im Sinne der Energieresonanzhypothese der heterogenen Katalyse diskutiert. Dabei wird ein Zusammenhang zwischen katalytischer Aktivität, Aktivierungsenergie der Homogenreaktion, in der Literatur beschriebenen Elektronenstoßversuchen in der Gasphase und der Ladungsträgerenergie des Katalysators festgestellt.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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