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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 327 (1964), S. 71-78 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On heating Na2HPO3 with surplus LiH at 330°C in N2 atmosphere, 22-36% of the P(III) compound are oxidized to hypophosphate. Furthermore, metaphosphite and orthophosphate (by disproportionation of Na2PO3 radicals), phosphide (by reduction of Na2HPO3), hydrogen, and Li3N are formed, but no PH3.
    Notes: Während des Erhitzens von Na2HPO3 mit einem Überschuß von LiH auf eine Temperatur von 330°C in Stickstoffatmosphäre werden 22-36% Na2HPO3 zu Subphosphat oxydiert. Außerdem entstehen Metaphosphit und Orthophosphat als Produkte der Disproportionierung der Radikale [Na2PO3]°, ferner Phosphid (Produkt der Reduktion von Na2HPO3) Wasserstoff, und Li3N, aber kein PH3.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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