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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 302 (1959), S. 1-9 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A method of preparing [Cr tn3]Cl3 (tn = NH2 · CH2 · CH2 · CH2 · NH2) by direct interaction between CrCl3 and trimethylene diamine is described. From the new compound, complex salts of the type [Cr tn3]X3 with X = Br-, J-, ClO-4, and NO-3 have been obtained.The absorption spectrum of [Cr tn3]+ is given. Attempts to isolate optical antipodes are described.
    Notes: Es wird eine Methode zur Darstellung von [Cr tn3]Cl3(tn = NH2 · CH2 · CH2 ·CH2 · NH2) in direkter Reaktion aus CrCl3 und Trimethylendiamin angegeben. Aus dem Chlorid erhält man durch Umfällen mit entsprechenden Säuren und Alkalisalzen [Cr tn3]X3 mit X = Br-, J-, ClO-4 und NO-3. Das Absorptionsspektrum von [Cr tn3]3+ wird mitgeteilt. Versuche zur Trennung in die optischen Antipoden werden beschrieben.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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