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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 223-231 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Raman and infrared spectra of [(CH3)2SiO]3 and [(CH3)2SiNH]3 are reported and the frequencies are assigned as far as possible. It is concluded from the spectra that both the molecules have symmetrie D3h. Accordingly the rings (SiO)3 and (SiN-)3 are planar. The influence of the SiOSi angle on the SiOSi frequencies is discussed.
    Notes: Die Raman- und Ultrarot-Spektren des [(CH3)3SiO]3 und [(CH3)3SiNH]3 werden mitgeteilt und weitgehende Frequenzzuordnungen vorgenommen. Die Spektren gestatten die Aussagen, daß in beiden Molekeln Symmetrie D3h, d. h. ein ebener (SiO)3- bzw. (SiN)3- Ring vorliegen. Der Einfluß des SiOSi-Winkels auf die SiO-Frequenzen wird diskutiert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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