ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The stabilities of tris-oxalato complexes of trivalent metals like Fe, Cr, Al, Ga have been studied. These compounds have been found to decompose in steps by interaction with acids. The stepwise instability constants and also the overall instability constants of the reactions MOx3‴ → MOx′2 + Ox″, MOx′2 → MOx+ + Ox″, MOx+ → M3+ + Ox″ and MOx3‴ → M3+ + 3 Ox″ have been measured.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19572930307