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Zerfall von 1-n-Butylaminocyclohexyl-phosphonsäure-di-n-butylester (Buminafos) in wäßrigem Medium (1991)

Schneider, B. ; Porzel, A. ; Weidhase, R. ; [et al.]

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 333 (1991), S. 85-90

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Degradation of n-Butylaminocyclohexyl phosphonic Acid di-n-Butylester (Buminafos) in Aqueous Medium.In aqueous medium, breakdown of Buminafos (1) is connected with total loss of its herbicidal activity. The phosphorus-carbon bond is cleaved and n-butylcyclohexylidene amine (3), cyclohexanone (5), phosphoric acid mono-n-butyl ester (4) (partly as n-butylamine salt), and 1-aminocyclohexyl phosphonic acid di-n-butylester (8) were found as degradation products of carbon-14 labeled Buminafos. Identification was performed by MS, GC/MS, 1H- and 31P-n.m.r. spectroscopy, by detection of phosphorus, and by means of the radioactivity.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19913330118

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